My Accolades card is my favorite card. The benefits are great, but best of all is the expedited, priority customer care you get.
You can just apply, but having a BofA account probably helps to get one. The application is fairly well hidden, but public:
https://wwwa.applyonlinenow.com/USCCapp/Ctl/entry?sc=FAA848
It is one of the few applications that I've seen ask for your income, employer, citizenship, etc.
They pulled two different CRAs when I applied.