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I'd normally say not to worry about it..and I really do think you'd be safe accepting the offer. However, a post here just a few days ago about an offer from Chase would have me be a bit more careful. Read the original post in the link below.
http://ficoforums.myfico.com/fico/board/message?board.id=creditcard&thread.id=162598
There was an article in our city newspaper today about a woman who is a longime Discover creditcard customer. They offered her zero interest balance for six months (which would increase to more than 9% after). The transfer went through, and two days later she received a notice from them saying the terms are changing and it was no longer a fixed rate.
That example is just bad business to me ... a true bait and switch. As my parents always said, "If it sounds too good to be true, it probably is." Be careful OP ... beware and be careful.
Edit to add: I realize my post is not about the CITI offer specifically, however just wanted to provide another example of what is happening in the current economic climate with 0% balance transfer offers and longtime customers with good history.
PupleHaze,
Thanks for your input. Although I was offered the BT by Citi, I think its highly relevant to expand the discussion to any "special offers to good customers" by any CCC.