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There's 2 interest rates for the card. The 20% is if you use the pay over time feature, the 30% is if you don't pay in full every month like you're supposed to.
I would say with your credit profile, you will get the approval if that is what you are asking. AMEX really wants people to have these things.
That APR applies if you "Pay Over Time" on the Preset Limit you are allowed. Essentially, its a line of credit without reporting as revolving. Everyone gets the 20.49% APR standard. You can have an 850 EX and still get 20.49%.
I would think you’d be good to go for that one. Prequals are pretty solid with Amex. Good luck!